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This is a cool way to use multiple login on your Gtalk….

1. Right Click the Gtalk Shortcut>Properties>shortcut
2.In shortcut tab there is one field called Target which has”C:\Program Files\Google\Google Talk\googletalk.exe” ( my default installer is on C drive)
3A. Now at the end of target add this “/nomutex” without the quotes.
3B. Make this target as “C:\Program Files\Google\Google Talk\googletalk.exe” /nomutex
There is a space after googletalk.exe”
4. Finished

Now for every click of Gtalk shortcuts you will have new Gtalk windows open with username and password.

Enjoy chat with multiple login id’s on gtalk.